منابع مشابه
Meso-meso linked corroles.
The cascade reaction of sterically hindered dipyrromethanes and formaldehyde furnished meso(10)-meso(10') linked corroles--a new type of porphyrinoid--compounds with interesting photophysical properties.
متن کاملOxo and imido/imido exchange and C–H activation reactions based on pentamethylcylopentadienyl imido tantalum complexes
Reactions of [TaCp*Cl4] with two, three and four equivalents of LiNH Bu give the haloand amido-imido complexes [TaCp*Cl2(N Bu)] (1a), [TaCp*Cl(NBu)(NHBu)] (2) and [TaCp*(NBu)(NHBu)2] (3), respectively. The related complex [TaCp*Cl2{N(2,6-Me2C6H3)}] (1b) is prepared by a similar reaction using two equivalents of Li[NH(2,6-Me2C6H3)]. Complex 3 can be transformed into 2 and further into 1a by reac...
متن کاملBipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes.
Seven bipyridine adducts of molybdenum imido alkylidene bispyrrolide complexes of the type Mo(NR)(CHCMe(2)R')(Pyr)(2)(bipy) (1a-1g; R = 2,6-i-Pr(2)C(6)H(3) (Ar), adamantyl (Ad), 2,6-Me(2)C(6)H(3) (Ar'), 2-i-PrC(6)H(4) (Ar(iPr)), 2-ClC(6)H(4) (Ar(Cl)), 2-t-BuC(6)H(4) (Ar(t) (Bu)), and 2-MesitylC(6)H(4) (Ar(M)), respectively; R' = Me, Ph) have been prepared using three different methods. Up to th...
متن کاملTerminal imido rhodium complexes.
Compounds of the late transition metals with M=X multiple bonds (X=CR2, NR, O) represent a synthetic challenge, partly overcome by preparative chemists, but with noticeable gaps in the second- and third-row elements. For example, there are no isolated examples of terminal imido rhodium complexes known to date. Described herein is the isolation, characterization, and some preliminary reactivity ...
متن کاملTransition Metal Imido Complexes
A wide range of transition metal imido (TMI) complexes is studied using ab initio molecular orbital (MO) calculations. The main computational point of interest is the further testing of effective core potentials (ECPs) and valence basis sets to allow for the accurate calculation of properties for reasonably sized transition metal complexes. On the chemical side, several results from the study a...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2020
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.0c00477